PP compounds

Halogen-free flame-retardant PP and flame-retardant glass-fiber-reinforced PP.

Example grade / typical values — to be corrected by GREENPOLYMER

Selection criteria

  • Density
  • Cost
  • Stiffness
  • Flame retardancy

PP (polypropylene) has low density, low cost and good chemical resistance. Standard PP burns easily; with flame retardant it is used for internal parts of home appliances, internal brackets of power supplies and charging equipment, cable ducts and fan parts. With glass fiber its stiffness and heat resistance rise markedly, so it can be used for structural parts that need flame retardancy.

GREENPOLYMER PP grades

GradeKey featuresSuitable parts
GRN-PP-N510Halogen-free flame-retardant PPInternal parts of home appliances, cable ducts, internal brackets of power supplies
GRN-PP-E510Flame-retardant glass-fiber-reinforced PPAppliance structural parts, fan parts, internal brackets of energy storage equipment
Food-contact PP (grade provided per project)Food contactElectric kettle bodies and lids, coffee machine water tanks, food-contact appliance parts

Recycled-content versions (-R) of each grade can be customized.

  • Food-contact grades available; compliance testing to GB 4806 and EU Regulation (EU) No 10/2011 can be arranged.

Key properties

Typical values. Refer to the actual TDS.

  • DensityISO 1183
    • PP-N5101.00–1.10 g/cm³
    • PP-E5101.15–1.30 g/cm³
  • MFRISO 1133
    • PP-N5105–20 g/10 min (230 °C / 2.16 kg)
    • PP-E5103–10 g/10 min (230 °C / 2.16 kg)
  • Tensile strengthISO 527
    • PP-N51020–28 MPa
    • PP-E51050–70 MPa
  • Flexural modulusISO 178
    • PP-N510—
    • PP-E5104–6 GPa
  • Notched impact (23 °C)ISO 179/1eA
    • PP-N5103–6 kJ/m²
    • PP-E5105–9 kJ/m²
  • HDT (1.80 MPa)ISO 75
    • PP-N51055–65 °C
    • PP-E510120–145 °C
  • Flammability (design target)UL 94
    • PP-N510V-0 @ 1.5 mm
    • PP-E510V-0 @ 1.5 mm
Full table
ItemTest standardGRN-PP-N510GRN-PP-E510
DensityISO 11831.00–1.10 g/cm³1.15–1.30 g/cm³
MFRISO 11335–20 g/10 min (230 °C / 2.16 kg)3–10 g/10 min (230 °C / 2.16 kg)
Tensile strengthISO 52720–28 MPa50–70 MPa
Flexural modulusISO 178—4–6 GPa
Notched impact (23 °C)ISO 179/1eA3–6 kJ/m²5–9 kJ/m²
HDT (1.80 MPa)ISO 7555–65 °C120–145 °C
Flammability (design target)UL 94V-0 @ 1.5 mmV-0 @ 1.5 mm

Flammability ratings are design targets, tested to the UL 94 method (to be verified by GREENPOLYMER). Certificate to be uploaded.

Flame-retardant PP or flame-retardant glass-fiber-reinforced PP

SituationRecommended
Internal parts with low loads that should be light and low costGRN-PP-N510
Structural parts needing stiffness or heat resistance above 80 °CGRN-PP-E510
Good impact performance neededBoth have fairly low impact; consider PC/ABS
Appearance partsFlame-retardant PP has a modest surface; evaluate it first for appearance parts

Strengths and limits of PP

  • Strengths

    Low density; low cost; resistant to acids, alkalis and most solvents; no strict drying needed.

  • Limits

    Unreinforced PP has low heat resistance; high shrinkage; flame-retardant PP has fairly low impact; the surface is hard to bond and hard to paint.

  • Halogen-free flame-retardant PP

    Its high flame-retardant loading can affect impact and surface. Watch for flame retardant blooming at high temperature and humidity; damp heat testing is recommended.

Processing advice

Typical values. Refer to the actual TDS.

Injection speed
GRN-PP-N510 Medium
GRN-PP-E510 Medium to fast
Residence time
GRN-PP-N510 As short as possible, to avoid degrading the flame retardant
GRN-PP-E510 As short as possible
Full table
ItemGRN-PP-N510GRN-PP-E510
DryingUsually not needed; if damp, 80 °C, 1–2 hSame
Melt temperature190–220 °C (not too high for flame-retardant grades)210–240 °C
Mold temperature30–60 °C40–70 °C
Injection speedMediumMedium to fast
Residence timeAs short as possible, to avoid degrading the flame retardantAs short as possible

Design points

  • High shrinkage

    Unreinforced PP shrinks about 1.5–2.0 % (typical value); size the mold to the material's shrinkage.

  • Glass-fiber-reinforced PP shrinks anisotropically

    It warps easily; watch the gate position and keep walls even.

  • Use ribs instead of thicker walls

    Thick walls cause sink marks.

  • Hinge design (unreinforced PP)

    PP suits living hinges, but hinge life in flame-retardant PP must be validated.

FAQ

Can flame-retardant PP replace flame-retardant ABS?

It can be considered for internal parts with no appearance or impact requirements, lowering weight and cost. For appearance parts and parts under impact, validate first.

Is there a food-contact PP?

Yes. Food-contact grades are available, with compliance testing supported to GB 4806 and (EU) No 10/2011 requirements. Tell us the service temperature, contact time, food type and target market; food-contact grades are provided per project.

Can flame-retardant PP be glow-wire tested?

Yes, to the IEC 60695-2-12/13 methods. For appliance parts, tell us the required glow-wire temperature.

Contact us

Tell us the part name, flammability rating and thickness, glow-wire requirements, operating temperature and the expected volume. Phone +86 18822892298 | Email hello@greenpolymer.com